Interplay of metal-allyl and metal-metal bonding in dimolybdenum allyl complexes.
نویسندگان
چکیده
Addition of PMe3 to Mo2(allyl)4 afforded Mo2(allyl)4(PMe3)2, in which two of the allyl groups adopt an unprecedented micro2-eta1,eta3 bonding mode; theoretical studies elucidate the roles of the sigma- and pi-donor ligands in the interplay of metal-allyl and metal-metal bonding.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 28 شماره
صفحات -
تاریخ انتشار 2009